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Annals of Occupational Hygiene Advance Access originally published online on March 11, 2009
Annals of Occupational Hygiene 2009 53(3):225-237; doi:10.1093/annhyg/mep002
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© 2009 The Author(s).
This is an Open Access article distributed under the terms of the Creative Commons Attribution Non-Commercial License (http://creativecommons.org/licenses/by-nc/2.0/uk/), which permits unrestricted non-commercial use, distribution, and reproduction in any medium, provided the original work is properly cited.

A Novel Size-Selective Airborne Particle Size Fractionating Instrument for Health Risk Evaluation

B. Gorbunov1, N. D. Priest2, R. B. Muir1,*, P. R. Jackson3 and H. Gnewuch1

1 Naneum Ltd, Suite BG10, CEH, University of Kent, Canterbury, Kent CT2 7NJ, UK
2 School of Health and Social Sciences, Middlesex University, Queensway, Enfield, Middlesex EN3 4SA, UK
3 CERAM, Queens Road, Penkhull, Stoke-on-Trent, Staffordshire ST4 7LQ, UK

* Author to whom correspondence should be addressed. Tel: +01227 824631; fax: +01227 827778; e-mail: robert.muir{at}naneum.com

Health risks associated with the inhalation of airborne particles are known to be influenced by particle size. Studies have shown that certain nanoparticles, with diameters <100 nm, have increased toxicity relative to larger particles of the same substance. A reliable, size-resolving sampler able to collect a wide range of particle sizes, including particles with sizes in the nanometre range, would be beneficial in investigating health risks associated with the inhalation of airborne particles. A review of current aerosol samplers used for size-resolved collection of airborne particles highlighted a number of limitations. These could be overcome by combining an inertial deposition impactor with a diffusion collector in a single device. Verified theories of diffusion and inertial deposition suggested an optimal design and operational regime. The instrument was designed for analysing mass distribution functions. Calibration was carried out using a number of recognized techniques. The sampler was tested in the field by collecting size-resolved samples of lead containing aerosols present at workplaces in factories producing crystal glass. The mass deposited on each screen proved sufficient to be detected and measured by an appropriate analytical technique. Mass concentration distribution functions of lead were produced. The nanofraction of lead in air varied from 10 to 70% by weight of total lead.

Keywords: Brownian diffusion • humidity • inertial deposition • nanoparticles • size-resolved chemical composition • PM10

Received June 15, 2008; in final form December 19, 2008


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